Our global eco-system is, essentially, carbon based. Thanks to sunlight, photosynthesis incorporates
atmospheric CO 2 into plants which, among others, serve as food for animals and humans. Up to 1 billion
tonnes of organic waste are globally produced each year and constitute an enormous potential for carbon
recovery. Complexity and variability being key characteristics of this waste, render its processing
challenging. Conversion to biogas holds promise as a manner to ‘simplify’ this carbon containing
resource by significantly reducing compositional variations. This allows further, larger-scale centralized
processing, e.g., according to the OBIWAN concept, of locally produced biogas.
OBIWAN comprises methane pyrolysis and CO 2 hydrogenation step, after prior separation of both
components from biogas, in its conversion to various value-added products. A minimum methane
content of 60% is required in the biogas for the amount of hydrogen obtained via methane pyrolysis to
be sufficient to hydrogenate all CO 2 to methanol. An ElectroThermal Fluidized Bed (ETFB) reactor,
fueled by renewable electricity, is an ideally suited candidate for driving this highly endothermic
reaction, simultaneously generating high quality solid carbon (useful for battery or tire applications) as
byproduct. CuZn based catalysts are the benchmark for CO 2 hydrogenation to methanol and are the
subject of high-throughput development. The obtained methanol serves as a starting material for
Sustainable Aviation Fuel (SAF) synthesis over innovative ZSM-5 zeolites, including cofeeding of
heavier alcohols or olefins.